Publications
2024
| 17 |
Series of Protonated Nitrogen Bases with a Weakly Coordinating Counteranion: Observation of the 14N–1H Spin–Spin CouplingACS Organic & Inorganic Au, 2024, 4, 1, 91–96. https://doi.org/10.1021/acsorginorgau.3c00045 Invited contribution to the special issue celebrating the ‘2023 Risings Stars Organic & Inorganic Chemistry’.
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2022
| 16 |
Oxygenation of Copper(I) Complexes Containing Fluorine Tagged Tripodal Tetradentate Chelates: Significant Ligand Electronic EffectsJournal of Coordination Chemistry, 2022, 75 (11–14), 1617–1635. https://doi.org/10.1080/00958972.2022.2107429 Invited contribution to the 2022 Emerging Leaders of Coordination Chemistry Issue.
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| 15 |
Insights into the Chemical Diversity of Selected Fungi from the Tza Itzá Cenote of the Yucatan PeninsulaCarlos A. Fajardo-Hernández, Firoz Shah Tuglak Khan, Laura Flores-Bocanegra, Alejandra Prieto-Davó, Baojie Wan, Rui Ma, Mallique Qader, Rodrigo Villanueva-Silva, Anahí Martínez-Cárdenas, Marian A. López-Lobato, Shabnam Hematian, Scott G. Franzblau, Huzefa A. Raja, Rodolfo García-Contreras and Mario Figueroa* ACS Omega, 2022, 7 (14), 12171–12185. https://doi.org/10.1021/acsomega.2c00544
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| 14 |
New Terpenoids from the Corticioid Fungus Punctularia atropurpurascens and their Antimycobacterial EvaluationDaniel Acero, Firoz Shah Tuglak Khan, Isabel Rivero-Cruz, Abraham J. Medina-Ortiz, Huzefa A. Raja, Laura Flores-Bocanegra, Carlos A. Fajardo-Hernández, Baojie Wan, Scott G. Franzblau, Shabnam Hematian and Mario Figueroa* Planta Medica, 2022, 88 (09/10), 729–734. https://www.doi.org/10.1055/a-1786-8072
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| 13 |
Dioxygen Reactivity of Copper(I)/Manganese(II)-Porphyrin Assemblies: Mechanistic Studies and Cooperative Activation of O2Molecules, 2022, 27 (3), 1000–1015. https://doi.org/10.3390/molecules27031000 Invited contribution to a Special Issue celebrating “25th Anniversary of Molecules – Featuring Element 25: Manganese and/or Other Metals”
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| 12 |
Structural Diversity of Perylenequinones is Driven by their Redox BehaviorZeinab Y. Al Subeh, Amy L. Waldbusser, Huzefa A. Raja, Cedric J. Pearce, Kin Lok Ho, Michael J. Hall, Michael R. Probert, Nicholas H. Oberlies,* and Shabnam Hematian* The Journal of Organic Chemistry, 2022, 87 (5), 2697–2710. https://doi.org/10.1021/acs.joc.1c02639
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2021
| 11 |
Protonation of the Oxo-Bridged Heme/Copper Assemblies: Modeling the Oxidized State of the Cytochrome c Oxidase Active SiteMaria C. Carrasco, Katherine J. Dezarn, Firoz Shah Tuglak Khan, and Shabnam Hematian* Journal of Inorganic Biochemistry, 2021, 225, 111593–111596. https://doi.org/10.1016/j.jinorgbio.2021.111593 Invited contribution to a Special Issue honoring “Professor Ken Karlin: Celebrating his 2021 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry.”
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| 10 |
Proton Relay in Iron Porphyrins for Hydrogen Evolution ReactionSarmistha Bhunia, Atanu Rana, Shabnam Hematian, Kenneth D. Karlin,* Abhishek Dey* Inorganic Chemistry, 2021, 60 (18), 13876–13887. https://doi.org/10.1021/acs.inorgchem.1c01079
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| 9 |
Synthetic, Spectroscopic, Structural, and Electrochemical Investigations of Ferricenium Derivatives with Weakly Coordinating Anions: Ion Pairing, Substituent, and Solvent EffectsMaria C. Carrasco, Hadi Pourhadi, and Shabnam Hematian* Dalton Transactions, 2021, 50 (21), 7433-7455. https://doi.org/10.1039/D1DT01192H
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2020
| 8 |
The Chemistry of Kratom [Mitragyna speciosa]: Updated Characterization Data and Methods to Elucidate Indole and Oxindole AlkaloidsLaura Flores-Bocanegra, Huzefa Raja, Tyler Graf, Mario Augustinović, Diane Wallace, Shabnam Hematian, Joshua J. Kellogg, Daniel A. Todd, Nadja B. Cech, and Nicholas H. Oberlies* Journal of Natural Products 2020, 83 (7), 2165–2177. https://doi.org/10.1021/acs.jnatprod.0c00257 |
2019
| 7 |
(Hydr)oxo-Bridged Heme Complexes: From Structure to ReactivityMaria C. Carrasco and Shabnam Hematian* Journal of Porphyrins and Phthalocyanines 2019, 23, 1286–1307. Invited contribution to a Special Issue on “Women in Porphyrin Science.” https://doi.org/10.1142/S1088424619300258
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2017
| 6 |
Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) DisproportionationShabnam Hematian, Gayan B. Wijeratne, Maxime A. Siegler, and Kenneth D. Karlin* Journal of the American Chemical Society 2017, 139 (38), 13276−13279. |
2015
| 5 |
Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e–/4H+ O2-ReductionSudipta Chatterjee, Kushal Sengupta, Shabnam Hematian, Kenneth D. Karlin,* and Abhishek Dey* Journal of the American Chemical Society 2015, 137 (40), 12897–12905. https://pubs.acs.org/doi/abs/10.1021/jacs.5b06513
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| 4 |
Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen OxidesShabnam Hematian, Isaac Garcia-Bosch, and Kenneth D. Karlin* Accounts of Chemical Research 2015, 48 (8), 2462–2474. https://pubs.acs.org/doi/10.1021/acs.accounts.5b00265
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| 3 |
Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-FeIII–O–CuII ConstructsShabnam Hematian, Isabell Kenkel, Tatyana E. Shubina, Maximilian Dürr, Jeffrey J. Liu, Maxime A. Siegler, Ivana Ivanovic-Burmazovic,* and Kenneth D. Karlin* Journal of the American Chemical Society 2015, 137 (20), 6602–6615. https://pubs.acs.org/doi/abs/10.1021/jacs.5b02174
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2014
| 2 |
Nitric Oxide Generation from Heme/Copper Assembly Mediated Nitrite Reductase ActivityShabnam Hematian, Maxime A. Siegler, and Kenneth D. Karlin* Journal of Biological Inorganic Chemistry 2014, 19, 515–528. https://doi.org/10.1007/s00775-013-1081-6
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2012
| 1 |
Heme/Copper Assembly Mediated Nitrite and Nitric Oxide InterconversionShabnam Hematian, Maxime A. Siegler, and Kenneth D. Karlin* Journal of the American Chemical Society 2012, 134 (46), 18912–18915. https://pubs.acs.org/doi/abs/10.1021/ja3083818
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